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So then I realised what people are talking about when they say you need REAL primer, not just any old model paint.
I've been using the Rustoleum Matt Black picked up from Wickes. Lately though I think temperature or something is causing an issue. It seems to not be giving good coverage. It comes out as looking as though the figures have been given several washes of black paint. Which is fine for chainmail etc, but it's not ideal.
I have had issues with Rustoleum Paint & Primner in that it doesn't adhere well to metals and lacks "tooth". On plastic it seems fine.