Looking at Assorted Automations, Walkers, land Ironclads, etc. for 19th Century (mostly VSF

but I want to try and stay in the 19th Century historical look as much as possible,)

I was debating which should be brass (automations?) or Iron (Walkers, Land Ironclads?) or Steel?

Brass would tarnish and Iron/Steel would rust so I could weather the pieces (I extremely rarely bother (simple painting is traumatic enough most of the time)

but these would be small units or singletons so I might justify the effort.
Also, why brass? Cost? Cool factor? Both might (in thick enough plates) deflect lead bullets I suspect. Would you need more weight/mass/thickness for brass to deflect the rifle bullets of the era?
Your thoughts on this subject of which metal color to use and why?
Gracias,
Glenn