I'm not familiar with Coat de Arms paints, but from what little google dredged up, it looks like they are water based acrylics.
If so, then that's maybe part of the problem (provided you've ruled out residual mold release and surface oils "sweating" from improperly mixed/cured resin). Depending on casting methods, resin can sometimes turn out with a super-smooth finish that provides no "tooth" and encourages high surface tension in water based paints. It's not a deficiency in the material, but rather in the casting technique: the ways to avoid it are to seal your masters with a satin/semigloss primer before molding, and/or to powder the molds with talc between castings (this also helps hugely with air bubble prevention).
If this is what you're dealing with, then priming with something oil based (i.e. enamel or lacquer) before switching to acrylics for actual painting would be the solution on your end. Oil based paints are more "gummy" while wet, so unusually high surface tension alone won't prevent them from sticking like it can for water based paints.
You want to always prime resin as a rule anyway, since resin is generally more chemically inert than polystyrene or metal.