Shaking will help resuspend the solids that settle to the bottom. After shaking, twist the bottles between your hands upside down or sideways to get the solids and resin medium mixed.
Since I bought an ultrasonic stirrer, I just use that and add some Vallejo matte medium, Vallejo thinner, or distilled water to thin it out. Let the device shake it for 30-45 seconds and all is well!
Adding a stainless steel or ceramic bearing or bead will also help when shaking and mixing. I've recovered 10+ year old bottles of Vallejo that had not gone completely dry using these techniques!
I am not aware of any paint that requires
no maintenance or mixing, including spray cans (shake before using), craft paints, or even household latex paint. Paint stirrers were created and sold for a reason.
Is that before, after or instead of shaking? I've had the problem as well recently. always with the same colours.