Thanks to all who took the time to offer suggested remidies, and I thought I should let you know how I went on.
The 1st thing I did was to spray the old can onto black card and I had loads of white spots, the can was almost empty. I also sprayed a new can onto the black card and it was fine. This was done at the same time indoors in a warm room, I wonder if it is the proportion of propellant to varnish that is causing the spots. i.e. when there is little varnish in the can then the white spots are more prevalent, or it may be as Deltadog suggests that the can interior coating is breaking down, it is probably 3 years since I 1st used it.
I tried 2 of the remedies suggested, the 1st was a cotton wool bud dipped in olive oil, rubbing each individual spot, this worked a treat, the white spots disappeared, I then washed the figure lightly in a mix of water and washing up liquid to remove the olive oil, this left me with a figure with a slight sheen. I then sprayed with the new can of army painter anti matt spray and it was fine. I worry a little about the fact that my figure will have some vegetable oil still on it and so will cause bacterial growth in the future.
Raoul De Nesle - Compte de Soissonis - spotlessThe 2nd I tried water to remove the spots, when wet they were invisible but when it dried they were still there, I then re-varnished the figure with my normal brush on varnish. This currently is Ronseal interior water based matt varnish, the stuff normally used on wood. This normally gives quite a good matt finish, and then sprayed with the new can of army painter anti matt spray and it was better but not cured.
David - Earl of Huntingdon not so spotlessI believe gloss varnish reflects the light because it is a solid surface, and that matt varnish is microscopically rough and so diffuses the light and so is appears matt. If this is the case the oil will fill up the rough surface therefore making the spot invisible and then the anti shine spray will break up light reflection and so a good result, maybe the fact that I used a matt varnish to overcoat the spots means they are still none reflective and so when sprayed with matt varnish didn’t get a good result. So maybe Chernos suggestion of using a gloss varnish would replicate the oil, but I don’t have any gloss varnish.
So it looks like some 100 figures will have to be dabbed with olive oil and washed and sprayed again. Bugger.