It is possible to get good castings with blue stuff /oyumaru, even fully detailed minis. If you have a solid frame (Lego work great) its much better. In my experience the key is in the way you fill the mold with epoxy putty. You need a tool to help you pack the material in and you have work in small little chunks. A silicone brush works the best. For very difficult spots you might need to wet them with a tiny bit of isopropanol. If you use big chunks and just hope that they will catch all the small details by pressing hard, it wont work. You will end up with tiny pockets of air. The good thing with epoxy is that the castings will be very hard. The bad is that it takes about 12 hours to cure.
The ''acrylic resin'' Greenstuffworld sells can be found in bigger quantities and better price. I have seen it been marketed as Jesmonite and White Stone. But as it was mentioned Im sure that Pebeo makes some too. I think its some kind of refined plaster/porcelain not an actual resin.
The best route is the one that goes through polyurethane resin and silicone molds. The problem is that many pros act like medieval blacksmiths and are too precious with their knowledge. A vacuum chamber can be easily made at home, you dont need all that super expensive acrylic sheet and pots. I managed to make one out of a big thick wide glass jar used for pickling vegetables. A vacuum pump would be ideal but even an old refrigerator motor will do the trick. My first attempt was with a hand pump

. It worked actually but... yeah...

I tried to cast resin with oyumaru (better and cheaper that Blued Stuff) but the exothermic reaction results to soft detail because the mold is softening up. There is a way to have cheap silicone molds by using a mix of construction silicone + starch. You can make a putty that will work for things like buildings and terrain. But its kinda messy.