I don't think any of the Shapeways stuff is really any good for minis. Most of it is too low res, too delicate, or both. The only material that I'd consider good enough detail wise is both delicate and plagued with various serious print QC issues that haven't appeared to have improved in the two years or so it's been offered. Some of their stuff is probably good for vehicles, but even there you'd probably have too do a lot of finishing work. Apart from the jewelry metals IMO Shapeways' actual utility seems limited to novelties and tech prototyping.
I'm not sure there's any printing tech or material currently that produces objects with the right combo of resolution, durability, and price needed for end-use products. Mostly I see people doing like Not Yet Dead: paying more for an industry-level service that can actually do good detail reliably, then using those prints as masters for casting.
It'll happen eventually. IMO the lack of quality economic printing options is pretty much all that's keeping traditional sculpting alive (apart from materials like stone, ceramic, or wood). In less than ten years (maybe even less than five) the pound of toy wax I just bought will be 100% obsolete. Kinda sucks right now during the awkward transition period though. I've got 28mm vehicle designs (among other things) I'd love to make real, but even the cheapest, crappiest materials are too expensive for anything over a few CC in volume.